Heat can add up and in my experience wire rated for >60C would be good and it's worth paying attention to actuals when the system is operating. Metal conduit and connection boxs don't help dissipate heat but conduit is required in my jurisdiction for DC 48v+ and I've had 2 incidences of arcing connections and have come to firmly believe in metal connection boxes.
It's about 150ft from my arrays to my charge controllers and the original electrician ran 2 x sets of 6awg in 1" conduit - e.g. 4 x individual wires. Originally I overplanneled and neared 4000w / 45a per pair of wires quite often in summer
and... neared 60C as measured in a connection box about 10ft from the charge controllers. When I expanded, I went with just 1 pair of 6awg per 1" conduit - partly to keep things cooler.
What was interesting to me, the heat increased as one got further from the PV and closer to the charge controllers. You could feel it by wrapping you're hand around the conduit as various places along the way - the heat noticeably increased. I still don't understand this - I was thinking the heat would be steady the whole length. Maybe I'm off base?
Here's a snap of the last 14 days.
The 1st number after the word
"Wire:" is the PV -> Charge Controller connection box temps in "C" about 140ft from the array combiner boxes.
9 days ago I hit a 51.3C max for that day and a few 50.0C, 50.6C numbers but things tends to stay <50C for the most part on hot summer days / max PV since I stopped overpanelling.
View attachment 33610
The 2nd number is the temp at the main + and - buss of the system - also in a metal control box.
The 3rd and 4th numbers are the temps in the wiring troughs under the Midnite Classic 150s.